Dibromidobis[2-(dicyclohexylphosphanyl)biphenyl-κP]palladium(II)
oleh: Yu-Qing Zhang, Fei-Fei Cen, Zhi-Qiang Wang, Ying-Fei Li, Chen Xu
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-10-01 |
Deskripsi
The title compound, [PdBr2(C24H31P)2], has a distorted trans square-planar coordination of the Pd atom, which occupies an inversion centre. The most important bond distances include Pd—P of 2.380 (2) Å and Pd—Br of 2.515 (2) Å. Weak intermolecular π–π interactions between the benzene rings of adjacent molecules [centroid–centroid distance = 3.949 (6) Å] are present via crystallographic inversion centres, resulting in a one-dimensional supramolecular architecture.