Tetrakis{μ3-2-[(2-hydroxyethyl)amino]ethanolato}tetrakis[chloridonickel(II)] methanol solvate
oleh: Youzhu Yu, Yuhua Guo, Lei Lv, Dacheng Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-07-01 |
Deskripsi
The complex molecule of the title compound, [Ni4(C4H10NO2)4Cl4]·CH3OH, consists of a cubane-like {Ni4O4} core in which each nickel(II) atom is six-coordinated in a distorted octahedral geometry by one N and four O atoms of three mono-deprotonated diethanolamine ligands and by a chloride anion. The molecular conformation is stabilized by intramolecular O—H...Cl bonds. In the crystal structure, complex molecules and methanol solvent molecules are linked into a three-dimensional network by N—H...Cl, N—H...O and O—H...Cl hydrogen-bonding interactions.