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Activated Carbon and Carbon Quantum Dots/Titanium Dioxide Composite Based on Waste Rice Noodles: Simultaneous Synthesis and Application in Water Pollution Control
oleh: Xinyan Jin, Ruijie Che, Jie Yang, Yan Liu, Xinbao Chen, Yunge Jiang, Jiaqi Liang, Shuoping Chen, Heping Su
Format: | Article |
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Diterbitkan: | MDPI AG 2022-01-01 |
Deskripsi
To achieve the full utilization of waste rice noodle (WRN) without secondary pollution, activated carbon (AC) and carbon quantum dots/titanium dioxide (CQDs/TiO<sub>2</sub>) composite were simultaneously synthesized by using WRN as raw material. Both of the two materials showed potential applications in water pollution control. The AC based on WRN displayed a porous spherical micro-morphology, which could absorb heavy metal elements like Pb(II) and Cr(VI) efficiently, with a maximum equilibrium uptake of 12.08 mg·g<sup>−1</sup> for Pb(II) and 9.36 mg·g<sup>−1</sup> for Cr(VI), respectively. The adsorption of the resulted AC could match the Freundlich adsorption isotherm and the pseudo-second-order kinetics mode. On the other hand, the CQDs/TiO<sub>2</sub> composite based on WRN displayed a high efficient photocatalytic degradation effect on various water-soluble dyes such as methylene blue, malachite green, methyl violet, basic fuchsin, and rhodamine B under visible light irradiation, which showed better photocatalytic performance than commercial TiO<sub>2</sub>. The introduction of CQDs based on WRN to TiO<sub>2</sub> could result in efficient electron-hole pair separation and enable more photogenerated electrons to reduce O<sub>2</sub> and more photogenerated holes to oxidize H<sub>2</sub>O or OH<sup>−</sup>, which could cause stronger abilities in producing O<sub>2</sub><sup>·−</sup> and ·OH radical and better photocatalytic activity.