The Theoretical Description of Cathodic Deposition of New Conducting Polymer Composite, Assisted by a Perrhenate of a Novel Triazolic Derivative
oleh: Volodymyr Valentynovych Tkach, Marta V. Kushnir, Nataliia M. Storoshchuk, Volodymyr V. Parchenko, Ilona I. Aksyonova, Vira M. Odyntsova, Olga V. Luganska, Petro I. Yagodynets
| Format: | Article |
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| Diterbitkan: | Universidade Federal de Mato Grosso do Sul 2020-06-01 |
Deskripsi
<p>The theoretical description of a new sandwich-like rhenium-based polymer composite cathodic electrodeposition has been given. The cathodic process is realized by perrhenate-ion electrochemical reduction to rhenium (IV) oxide, acting as an in situ formed oxidant for 3,4-dimethoxypyrrole polymerization. It is shown that the polymer deposition in this system is realized by more efficient manner than during the direct electropolymerization. The polymer composite has to have a well-developed morphology and enhanced conductivity by sandwich-like structure. The oscillatory behavior, in this case, is also possible, being caused by the DEL influences on both electrochemical and chemical stages of the process.</p><p> </p><p>DOI: <a href="http://dx.doi.org/10.17807/orbital.v12i2.1193">http://dx.doi.org/10.17807/orbital.v12i2.1193</a></p>