Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection
oleh: Daofu Yuan, Yin Huang, Wentao Chen, Hailin Zhao, Shengrui Yu, Chang Luo, Yuxin Tan, Siwen Wang, Xingan Wang, Zhigang Sun, Xueming Yang
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2020-07-01 |
Deskripsi
The geometric phase effect associated with a conical intersection between the ground and first excited electronic state has been predicted in the H3 system below the conical intersection energy. The authors, by a crossed molecular beam technique and quantum dynamic calculations, provide experimental evidence and insight into its origin.