Tetrakis[tris(2,2′-bi-1H-benzimidazole)nickel(II)] bis(phosphate) sulfate
oleh: Chun-Sheng Ling, Lin Yan
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-11-01 |
Deskripsi
The title compound, [Ni(C14H10N4)3]4(PO4)2(SO4), consists of [Ni(C14H10N4)3]2+ complex cations (.3. symmetry) and disordered anions ({overline 4} symmetry) with occupancy factors of two-thirds for PO43− and one-third for SO42−. The Ni2+ centre is chelated by three bidentate 2,2′-bi-1H-benzimidazole molecules in a distorted octahedral coordination. N—H...O hydrogen bonds consolidate the building units into a framework structure.