Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts

oleh: Ferenc Kovács, Hui Yan, Heng Li, Sándor Kunsági-Máté

Format: Article
Diterbitkan: MDPI AG 2021-11-01

Deskripsi

The hydrogen bond structure of water was examined by comparing the temperature dependent OH-stretching bands of water and aqueous NaClO<sub>4</sub>, KClO<sub>4</sub>, Na<sub>2</sub>SO<sub>4</sub>, and K<sub>2</sub>SO<sub>4</sub> solutions. Results called attention to the role of cations on top of the importance of anions determining the emerging structure of a multi-layered system consisting single water rings or multi-ring water-clusters.