(Acetylacetonato-κ2O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ3N,N′,O)oxidovanadium(IV)
oleh: Fu-Ming Wang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-05-01 |
Deskripsi
The VIV atom in the title complex, [V(C11H13BrClN2O)(C5H7O2)O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetylacetonate anion, forming a distorted cis-VN2O4 octahedral coordination geometry. The deviation of the V atom from the plane defined by the three donor atoms of the Schiff base ligand and one O atom of the acetylacetone ligand towards the oxide O atom is 0.256 (2) Å.