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Bis[methyl 2-(2-pyridylmethylidene)hydrazinecarbodithioato]zinc(II)
oleh: Yue-Peng Cai, Xiao-Ming Lin, Jian-Qiao Chen, Zheng-Yuan Zhou, Xiu-Xia Zhou
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2008-02-01 |
Deskripsi
In the title compound, [Zn(C8H8N3S2)2], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiolate S atom; the coordination geometry is distorted octahedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The molecules are linked by C—H...S hydrogen bonds, forming a three-dimensional network structure.