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Applying the lithium iron phosphate battery online monitoring system to the DC power supply system of the substation is an innovative measure for energy saving and environmental protection of power enterprises. Nowadays, the world is advocating the use of energy-saving and environmentally-friendly green resources, which undoubtedly opens up a wider space for the research of lithium iron phosphate batteries. The article focuses on the performance analysis of the lithium iron phosphate battery system, the research significance, the composition of the system and the key technologies used.