Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
oleh: Guo-Bin Liu, Hong-Yun Zhao
| Format: | Article |
|---|---|
| Diterbitkan: | Beilstein-Institut 2008-07-01 |
Deskripsi
Ru3(CO)12/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru3(CO)12 and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 °C in good and high yields.