Cascade cyclization of alkene-tethered acylsilanes and allylic sulfones enabled by unproductive energy transfer photocatalysis
oleh: Yunxiao Zhang, Yizhi Zhang, Chen Ye, Xiaotian Qi, Li-Zhu Wu, Xiao Shen
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2022-10-01 |
Deskripsi
Acylsilanes decompose under light irradiation, and this limits their use in light-induced organic transformations. Here the authors report a strategy to inhibit the light-induced decomposition of acylsilanes, enabling the photochemical synthesis of cyclopentanol derivatives from alkene-tethered acylsilanes and allylic sulfones.