Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III)
oleh: Daopeng Zhang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-12-01 |
Deskripsi
The title compound, [Mn(C16H14N2O2)(NCO)], is a monoclinic polymorph of the previously published orthorhombic form [Lu et al. (2006). Inorg. Chem. 45, 3538–3548]. The MnIII ion is chelated by a tetradentate Schiff base ligand and coordinated by the N atom of a cyanate ligand in a distorted square-pyramidal arrangement. In the crystal, there are short intermolecular Mn...Ophenolate distances of 2.752 (3) Å between pairs of inversion-related molecules.