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The classical Hermite-Hermite matrix polynomials for commutative matrices were first studied by Metwally et al. (2008). Our goal is to derive their basic properties including the orthogonality properties and Rodrigues formula. Furthermore, we define a new polynomial associated with the Hermite-Hermite matrix polynomials and establish the matrix differential equation associated with these polynomials. We give the addition theorems, multiplication theorems and summation formula for the Hermite-Hermite matrix polynomials. Finally, we establish general families and several new results concerning generalized Hermite-Hermite matrix polynomials.