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Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatocobalt(II) dihydrate
oleh: Yu-xian Li, Da-wei Li, Dong Zhao
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2011-08-01 |
Deskripsi
In the title complex, [Co(SO4)(C9H8N6)(H2O)4]·2H2O, the CoII ion is six-coordinated by one N atom from a 1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole ligand, one O atom from a monodentate sulfate ligand and four water molecules in a slightly distorted octahedral geometry. The sulfate ligand is rotationally disordered over two sets of sites with refined occupancies of 0.662 (15) and 0.338 (15). In the crystal, complex molecules and solvent water molecules are linked through intermolecular O—H...O and O—H...N hydrogen bonds into a three-dimensional network.