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The activation of persulfate (PS) by Fe(III) for the removal of environmental organic pollutants was severely limited by the low reduction rate from Fe(III) to Fe(II). In present study, we reported that reducing sulfur species (i.e., SO₃²⁻, HSO₃⁻, S²⁻, and HS⁻) under low concentration could significantly accelerate the Fe(III)/Fe(II) cycle in the Fe(III)/PS system. Under the condition of 1.0 mM Fe(III) and 4.0 mM PS, the removal performance of Fe(III)/PS system was poor, and only 21.6% of BPA was removed within 40 min. However, the degradation efficiency of BPA increased to 66.0%, 65.5%, 72.9% and 82.7% with the addition of 1.0 mM SO₃²⁻, HSO₃⁻, S²⁻, and HS⁻, respectively. The degradation efficiency of BPA was highly dependent on solution pH and the concentration of reducing sulfur species. When the reductant was excessive, the removal efficiency would be significantly inhibited due to the elimination of reactive species. This study provided some valuable insights for the treatment of organic wastewater containing these inorganic reducing ions.