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There are two 2-phenylimidazole cations and two acetate anions in the asymmetric unit of the title molecular salt, C9H9N2+·C2H3O2−. The dihredral angles between the five- and six-membered rings are 5.50 (2) and 6.90 (2)° in the two molecules. The structure is stabilized by N—H...O and weak C—H...O hydrogen-bonding interactions between the cations and anions, resulting in chains propagating in [110].