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The deterioration of mortar has an adverse impact on the deformation and stress state of the masonry arch dam, after freeze-thaw cycles, in long-term operation. The purpose of this paper is to investigate the effect of reinforcement grouting on the stress of a thin masonry arch dam and propose a reasonable grouting method in the case of mortar deterioration. The determination of the ultimate grouting pressure is another main focus. The masonry material was generalized by combining a linear elastic model and the proportional weighted average under the condition of deterioration caused by freeze-thaw cycles. A series of analytical methods were proposed for the research of grouting effect on dam stress, based on which the ultimate grouting pressure is calculated in various cases. Results demonstrate that the dam tensile stress may exceed the allowable value in the following operation. Then, some recommended methods for the grouting layout and the estimation of grouting pressure were put forward by integrating the grouting field test with numerical analysis for reinforcement. The research conclusions might have a guiding significance for the reinforcement of similar projects.