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A percentage of natural fibers is used for developing a composite, the materials are quite increasing in recent trends, and they can be a potential replacement of synthetic fibers in the reinforcement phase of hybrid composite. In this research, the combination of natural fibers and synthetic fibers can be used as reinforcement, and epoxy polymer can be used as matrix material. The fibers of Kevlar and Napier grass are reinforced with epoxy matrix to develop a new composite by using conventional hand layup fabrication process and to quantify the effect of this hybrid composite laminate, with five different sequences following. To identify the mechanical properties of this hybrid composite through tensile, flexural, compression strength, impact strength, and hardness tests, among all five samples, sample A was given the maximum mechanical strength, such that the tensile strength is 210 MPa, flexural strength is 165 MPa, the impact energy absorption is 23 J, the average is 40% over the other samples, and, at the same time, the compression strength of sample E is 19 MPa, revealing the negative influence of hybrid composite. The SEM morphology was carried out to identify the failure mode of the hybrid composites.