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Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cadmium(II) propane-1,3-diol solvate
oleh: Kai-Long Zhong, Jiang-Dong Cui
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2010-07-01 |
Deskripsi
In the title compound, [Cd(SO4)(C12H8N2)2]·C3H8O2, the CdII atom has a distorted octahedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. The two chelating NCCN groups subtend a dihedral angle of 82.21 (9)°. The CdII ion, the S atom and the middle C atom of the propane-1,3-diol solvent molecule are located on special positions, site symmetry 2. The solvate features a pair of O—H...O hydrogen bonds with the uncoordinated O atoms of the sulfate ion. The OH group of the propane-1,3-diol solvent is disordered over two positions of equal occupancy.