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Reconsidering the role of the matter in the design process, with all its morphological ecosystemic and functional quality, is the starting point for the experimentation on innovative bioplastics conducted in industrial partnership by ZEBtwdZEEB Research Group of ‘L. Vanvitelli’ University of Campania with Service Biotech Srl. The use of the Scanning Electron Microscope (SEM) allowed evaluating the biological evolutionary dynamics at micro-level that are at the base of the experimentation, fully in line with the approach of the regenerative Design and the Ecotechnological Design.