Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-N-(4-fluorophenyl)methanimine
oleh: Musa A. Said, Bayan L. Al Belewi, David L. Hughes
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2015-01-01 |
Deskripsi
In the title compound, C22H21FNO3P, a 1,3,2-dioxaphosphinan-2-yloxy derivative, three O atoms are bonded in a trigonal–pyramidal manner to the P atom. The exocyclic P—O bond is significantly longer than the two endocyclic P—O bonds, viz. 1.6678 (12) Å compared to 1.6046 (13) and 1.6096 (12) Å. The six-membered ring which includes the P atom has a chair conformation. The fluorophenyl ring is inclined to the naphthalene ring system by 24.42 (7)°. In the crystal, molecules are linked via C—H...π interactions, forming slabs lying parallel to (10-1).