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Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ2N,N′}nickel(II) tetrahydrate
oleh: Chao-Zhu Li, Xue-Ren Huang
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2012-06-01 |
Deskripsi
In the title complex, [Ni(C12H9N2O3S)2(H2O)2]·4H2O, the NiII ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methylideneamino]benzenesulfonate ligands and two O atoms from cis-related water molecules in a slightly distorted octahedral environment [Ni—N = 2.071 (3)–2.121 (3) Å and Ni—O = 2.071 (2) and 2.073 (3) Å]. In the crystal, the coordinated water molecules and the four water molecules of solvation are involved in intermolecular O—H...O hydrogen-bonding interactions with water and sulfonate O-atom acceptors, giving a three-dimensional framework structure.