Rational design of carbon nitride photocatalysts by identification of cyanamide defects as catalytically relevant sites

oleh: Vincent Wing-hei Lau, Igor Moudrakovski, Tiago Botari, Simon Weinberger, Maria B. Mesch, Viola Duppel, Jürgen Senker, Volker Blum, Bettina V. Lotsch

Format: Article
Diterbitkan: Nature Portfolio 2016-07-01

Deskripsi

Graphitic carbon nitride is a promising hydrogen evolution photocatalyst, although there is limited understanding of its mechanistic operation. Here, the authors employ molecular heptazine-based model catalysts to identify catalytically relevant defects and to rationally design a highly active carbon nitride photocatalyst.