Synthesis of D-manno-heptulose via a cascade aldol/hemiketalization reaction
oleh: Yan Chen, Xiaoman Wang, Junchang Wang, You Yang
| Format: | Article |
|---|---|
| Diterbitkan: | Beilstein-Institut 2017-04-01 |
Deskripsi
A [4 + 3] synthesis of D-manno-heptulose is described. The cascade aldol/hemiketalization reaction of a C4 aldehyde with a C3 ketone provides the differentially protected ketoheptose building block, which can be further reacted to furnish target D-manno-heptulose.