Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]
oleh: Rajni Kant, Vivek K. Gupta, Kamini Kapoor, P. Valarmathi, S. Thirumaran
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-01-01 |
Deskripsi
In the centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one CdII atom and forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring CdII atoms, forming extended eight-membered C2S4Cd2 tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the CdII atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8).