Enhancing Hydrophilicity of Thick Electrodes for High Energy Density Aqueous Batteries

oleh: Jungeun Lee, Hyeonsoo Lee, Cheol Bak, Youngsun Hong, Daeha Joung, Jeong Beom Ko, Yong Min Lee, Chanhoon Kim

Format: Article
Diterbitkan: SpringerOpen 2023-04-01

Deskripsi

Highlights Sulfonated polyvinylidene fluoride (S-PVdF) binders with improved hydrophilicity were synthesized via a simple sulfonation process of conventional hydrophobic PVdF binders. The abundant sulfonate groups of S-PVdF binders significantly improved ionic conduction in thick electrodes (~ 6 mg cm−2), enabling improved reversible capacities under various current densities. The S-PVdF binders effectively suppressed cathode dissolution, resulting in enhanced capacity retention at higher temperature operations (45 °C).