μ-Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]chromium(III)} bis(hexafluoridophosphate)
oleh: Sheng Li, Shou-Bin Wang, Fu-Li Zhang, Kun Tang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-01-01 |
Deskripsi
The title compound, [Cr2Cl2O(C18H18N4)2](PF6)2, is isostructural with the VIII analogue. Each CrIII atom is chelated by the tetradentate tris(2-pyridylmethyl)amine ligand via four N atoms, and further coordinated by one Cl atom and one bridging O atom, giving a slightly distorted octahedral coordination geometry. The dinuclear complex is centrosymmetric, with the bridging O atom lying on a centre of inversion.