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4-{2-[2-(4-Formylphenoxy)ethoxy]ethoxy}benzaldehyde
oleh: Zhen Ma, Yiqun Cao
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2011-06-01 |
Deskripsi
The title compound, C18H18O5, was obtained by the reaction of 4-hydroxybenzaldehyde with bis(2,2-dichloroethyl) ether in dimethylformamide. In the crystal, the molecule lies on a twofold rotation axis that passes through the central O atom of the aliphatic chain, thus leading to one half-molecule being present per asymmetric unit. The carbonyl, aryl and O—CH2—CH2 groups are almost coplanar, with an r.m.s. deviation of 0.030 Å. The aromatic rings are approximately perpendicular to each other, forming a dihedral angle of 78.31 sh;H...O hydrogen bonds and C—H...π interactions help to consolidate the three-dimensional network.