(η6-p-Cymene)bis(trichloridostannyl)(triethoxyphosphine-κP)ruthenium(II)
oleh: Sergey S. Shapovalov, Bruno Therrien
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-11-01 |
Deskripsi
In the title complex, [RuSn2(C10H14)Cl6(C6H15O3P)], the Ru—Sn bond lengths [2.5619 (3) and 2.5669 (3) Å] are about 0.3 Å shorter than the sum of the covalent Ru and Sn radii (1.46 + 1.39 = 2.85 Å), in line with other structurally characterized arene ruthenium trichloridostannyl derivatives. The Ru(II) atom is surrounded by a para-cymene, a triethylphosphite and two trichloridostannyl ligands in a typical piano-stool coordination.