trans-Dichloridobis[tris(4-methoxyphenyl)phosphane]palladium(II) toluene solvate
oleh: Alfred Muller, Reinout Meijboom
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-11-01 |
Deskripsi
In the title compound, trans-[PdCl2{P(4-MeOC6H4)3}2]·C7H8, the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry. The Pd—P and Pd—Cl bond lengths are 2.3409 (4) and 2.2981 (4) Å, respectively. An intramolecular C—H...Cl hydrogen bond occurs. In the crystal, weak C—H...O interactions are observed between the aromatic rings of adjacent molecules. The toluene solvate molecule is equally disordered over two sets of sites.