Stereoselective gridization and polygridization with centrosymmetric molecular packing

oleh: Dongqing Lin, Ying Wei, Aizhong Peng, He Zhang, Chunxiao Zhong, Dan Lu, Hao Zhang, Xiangping Zheng, Lei Yang, Quanyou Feng, Linghai Xie, Wei Huang

Format: Article
Diterbitkan: Nature Portfolio 2020-04-01

Deskripsi

Gridarenes with well-defined edges and vertices represent versatile nanoscale building blocks for installating frameworks but suffer from lack of stereoselective control during their synthesis. Here, the authors report a diastereoselective gridization of superelectrophilic diazafluorene-containing substrates with crescent shapes into Drawing Hands grids (DHGs).