Rhodium-catalyzed triarylphosphine synthesis via cross-coupling of aryl iodides and acylphosphines
oleh: Jiefang Yang, Hongyu Wu, Zhiqian Wang
| Format: | Article |
|---|---|
| Diterbitkan: | Elsevier 2018-01-01 |
Deskripsi
Rhodium(I)-catalyzed C–P cross-coupling reaction with aryl iodides and acylphosphines was disclosed for a straight forward synthesis of triarylphosphines. The acylphosphines were successfully employed as both the phosphorus source and the ligand to the Rh(I) catalyst. The triarylphosphines could be afforded in a yield up to 98% with good toleration of wide functional groups.