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The study provides an in-depth study on the gas adsorption and transport behaviors of MOF glass membranes for the first time. Temperature dependance of gas permeability, adsorption coefficients and diffusion coefficients between 298 ​K and 313 ​K for TIF-4 and ZIF-62 glass membrane were evaluated. The CO2 permeability was dominated by the adsorption process, while CH4 transport was mainly driven by the activated diffusion. Further, the MOF glass membranes exhibited significant entropic selectivity in adsorption, along with notable enthalpic selectivity in diffusion.