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trans-Dichloridobis(quinoline-κN)platinum(II)
oleh: Kwang Ha
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-05-01 |
Deskripsi
In the title complex, trans-[PtCl2(C9H7N)2], the PtII ion is four-coordinated in an essentially square-planar coordination environment defined by two N atoms from two quinoline (qu) ligands and two Cl− anions. The Pt atom is located on an inversion centre and thus the asymmetric unit contains one half of the complex; the PtN2Cl2 unit is exactly planar. The dihedral angle between the PtN2Cl2 unit and the quinoline ligand is 85.1 (1)°. In the crystal, the complex molecules are stacked into columns along the b axis. In the columns, several intermolecular π–π interactions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.733 (5) Å between pyridine rings.