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Preparation of Porous Activated Carbons for High Performance Supercapacitors from Taixi Anthracite by Multi-Stage Activation
oleh: Xiao-Ming Yue, Zhao-Yang An, Mei Ye, Zi-Jing Liu, Cui-Cui Xiao, Yong Huang, Yu-Jia Han, Shuang-Quan Zhang, Jun-Sheng Zhu
Format: | Article |
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Diterbitkan: | MDPI AG 2019-10-01 |
Deskripsi
Coal-based porous materials for supercapacitors were successfully prepared using Taixi anthracite (TXA) by multi-stage activation. The characterization and electrochemical tests of activated carbons (ACs) prepared in different stages demonstrated that the AC from the third-stage activation (AC<sub>III</sub>) shows good porous structures and excellent electrochemical performances. AC<sub>III</sub> exhibited a fine specific capacitance of 199 F g<sup>−1</sup> at a current density of 1 A g<sup>−1</sup> in the three-electrode system, with 6 mol L<sup>−1</sup> KOH as the electrolyte. The specific capacitance of AC<sub>III</sub> remained 190 F g<sup>−1</sup> even despite increasing the current density to 5 A g<sup>−1</sup>, indicating a good rate of electrochemical performance. Moreover, its specific capacitance remained at 98.1% of the initial value after 5000 galvanostatic charge-discharge (GCD) cycle tests at a current density of 1 A g<sup>−1</sup>, suggesting that the AC<sub>III</sub> has excellent cycle performance as electrode materials for supercapacitors. This study provides a promising approach for fabricating high performance electrode materials from high-rank coals, which could facilitate efficient and clean utilization of high-rank coals.