Tris(2,2′-bi-1H-imidazole-κ2N3,N3′)cobalt(II) hydrogen phosphate
oleh: Qinhe Pan, Xia Zhi, Qihui Wu, Zhiqiang Liang, Fuxiang Wang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-10-01 |
Deskripsi
The title compound, [Co(C6H6N4)3]HPO4, was synthesized under hydrothermal conditions. In the cation, the CoII atom is octahedrally coordinated by six N atoms from three 2,2′-bi-1H-imidazole ligands [Co—N bond lengths are in the range 2.084 (5)–2.133 (6) Å]. Intermolecular N—H...O hydrogen bonds form an extensive hydrogen-bonding network, which links cations and anions into a three-dimensional crystal structure.