Chloridobis{N-[(dimethylamino)dimethylsilyl]-2,6-dimethylanilido-κ2N,N′}iron(III)
oleh: Juan Chen
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-07-01 |
Deskripsi
The title iron(III) compound, [Fe(C12H21N2Si)2Cl], is monomeric. The Fe atom is N,N′-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe—Namino bond is longer than the Fe—Nanilide bond by about 0.37 Å. The molecule displays a pseudo-twofold rotation. The five–coordinate Fe atom demonstrates a highly distorted trigonal–bipyramidal geometry.