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The act of accessing the exact location, or position, of a node in a network is known as the localization of a network. In this methodology, the precise location of each node within a network can be made in the terms of certain chosen nodes in a subset. This subset is known as the locating set and its minimum cardinality is called the locating number of a network. The generalized hexagonal cellular network is a novel structure for the planning and analysis of a network. In this work, we considered conducting the localization of a generalized hexagonal cellular network. Moreover, we determined and proved the exact locating number for this network. Furthermore, in this technique, each node of a generalized hexagonal cellular network can be accessed uniquely. Lastly, we also discussed the generalized version of the locating set and locating number.