Decacarbonyl[μ4-(ethane-1,2-diyldinitrilo)tetrakis(methanethiolato)]bis(triphenylphosphane)tetrairon(2 Fe—Fe)
oleh: Wei-Ming Gao, Jia-Ming Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-02-01 |
Deskripsi
In the title compound, [Fe4(C6H12N2S4)(C18H15P)2(CO)10], the unit cell contains one molecule, which exhibits a crystallographically imposed center of symmetry. The independent Fe2S2 fragment [Fe—Fe = 2.527 (1) Å] is in a butterfly conformation, and each Fe atom displays a pseudo-square-pyramidal coordination geometry. The phosphane group occupies an apical position [Fe—P = 2.2670 (14) Å]. In the crystal, weak intermolecular C—H...O hydrogen bonds link the molecules into chains along [110].