Crystal structure of 3,4-dichloroanilinium hydrogen phthalate

oleh: Muhammad Shahid, Muhammad Nawaz Tahir, Muhammad Salim, Munawar Ali Munawar

Format: Article
Diterbitkan: International Union of Crystallography 2015-07-01

Deskripsi

In the title salt, C6H6Cl2N+·C8H5O4−, the carboxylic acid and carboxylate groups of the anion form dihedral angles of 20.79 (19) and 74.76 (14)°, respectively, with the plane of the benzene ring. In the crystal, molecules are assembled into a two-dimensional polymeric network parallel to (100) via N—H...O and O—H...O hydrogen bonds. In addition, within the layer, there are π–π stacking interactions between the benzene rings of the cation and the anion [centroid–centroid distance = 3.6794 (17) Å]. A weak C—H...O interaction is also observed.