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Controllable Synthesis and Charge Density Wave Phase Transitions of Two-Dimensional 1T-TaS<sub>2</sub> Crystals
oleh: Xiaoguang Pan, Tianwen Yang, Hangxin Bai, Jiangbo Peng, Lujie Li, Fangli Jing, Hailong Qiu, Hongjun Liu, Zhanggui Hu
Format: | Article |
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Diterbitkan: | MDPI AG 2023-06-01 |
Deskripsi
1T-TaS<sub>2</sub> has attracted much attention recently due to its abundant charge density wave phases. In this work, high-quality two-dimensional 1T-TaS<sub>2</sub> crystals were successfully synthesized by a chemical vapor deposition method with controllable layer numbers, confirmed by the structural characterization. Based on the as-grown samples, their thickness-dependency nearly commensurate charge density wave/commensurate charge density wave phase transitions was revealed by the combination of the temperature-dependent resistance measurements and Raman spectra. The phase transition temperature increased with increasing thickness, but no apparent phase transition was found on the 2~3 nm thick crystals from temperature-dependent Raman spectra. The transition hysteresis loops due to temperature-dependent resistance changes of 1T-TaS<sub>2</sub> can be used for memory devices and oscillators, making 1T-TaS<sub>2</sub> a promising material for various electronic applications.