A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group
oleh: Miao Zhan, Zhengwei Ding, Shaozhi Du, Haohua Chen, Chao Feng, Ming Xu, Zhi Liu, Mengxi Zhang, Chao Wu, Yu Lan, Pengfei Li
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2020-02-01 |
Deskripsi
Predictable and unified approaches to all possible stereoisomers of acyclic compounds with contiguous stereocentres are rare. Here, the authors disclose a divergent α-functionalization of enolates with either syn or anti selectivity employing a β-boronyl group as a small, directing handle.