[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]bis(thiocyanato-κN)cadmium(II)
oleh: Yan Hui Chi, Lu Yi Zheng
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-01-01 |
Deskripsi
In the title complex, [Cd(NCS)2(C22H20N6)], the CdII ion is in a CdN6 coordination geometry which is intermediate between octahedral and trigonal–prismatic. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (13)°. In the crystal, there is a π–π stacking interaction involving two symmetry-related pyrazole rings, with a centroid–centroid distance of 3.664 (3) Å. In addition, there is a relatively short intermolecular contact between C atoms [C...C = 3.399 (6) Å] involving symmetry-related pyridine rings along the a axis.