Bis[(diphenylphosphanylmethyl)diphenylphosphane sulfide-κ2P,S]copper(I) hexafluoridophosphate
oleh: Jing-Jing Zhang, Feng Hu, Tai-Ke Duan, Qun Chen, Qian-Feng Zhang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-06-01 |
Deskripsi
In the title compound, [Cu(C25H22P2S)2]PF6, the CuI atom, lying on a twofold rotation axis, adopts a distorted tetrahedral geometry. The (diphenylphosphanylmethyl)diphenylphosphane sulfide ligand coordinates to the CuI atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF6− anion also lies on a twofold rotation axis.