Aquabis(4-methylbenzoato)-κO;κ2O,O′-bis(pyridine-κN)nickel(II)

oleh: Li-Li Ji, Hao Wang, Wen-Dong Song

Format: Article
Diterbitkan: International Union of Crystallography 2008-04-01

Deskripsi

In the title mononuclear complex, [Ni(C8H7O2)2(C5H5N)2(H2O)], the NiII atom is in a distorted octahedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methylbenzoate ligand and one monodentate 4-methylbenzoate ligand, two N atoms from pyridine ligands, axially positioned, and a water molecule. The equatorially positioned water molecule and uncoordinated carboxylate O atom form an intramolecular hydrogen bond. An intermolecular O—H...O hydrogen bond between the coordinated water molecule and carboxylate O atom of the 4-methylbenzoate ligand forms infinite chains along the b axis. These chains are connected by C—H...π interactions.