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Triaqua(1,10-phenanthroline-2,9-dicarboxylato)cobalt(II) dihydrate
oleh: Zi-Fa Shi, Zhu-Qing Gao, Jin-Zhong Gu
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2010-04-01 |
Deskripsi
The title compound, [Co(C14H6N2O4)(H2O)3]·2H2O, has twofold crystallographic symmetry. The CoII atom is in a distorted pentagonal-bipyramidal coordination environment with two N atoms and two O atoms from a tetradentate 1,10-phenanthroline-2,9-dicarboxylate ligand and one O atom from a water molecule forming the pentagonal plane, and two O atoms from two water molecules occupying axial positions. In the crystal, adjacent molecules are linked by O—H...O hydrogen bonds, forming a three-dimensional network.