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Introduction: Fractional nonlinear models have been widely used in the research of nonlinear science. A fractional nonlinear Schrödinger equation with distributed coefficients is considered to describe the propagation of pi-second pulses in inhomogeneous fiber systems. However, soliton molecules based on the fractional nonlinear Schrödinger equation are hardly reported although many fractional soliton structures have been studied. Objectives: This paper discusses the propagation and interaction between special fractional soliton and soliton molecules based on analytical solutions of a fractional nonlinear Schrödinger equation. Methods: Two analytical methods, including the variable-coefficient fractional mapping method and Hirota method with the modified Riemann–Liouville fractional derivative rule, are used to obtain analytical non-travelling wave solutions and multi-soliton approximate solutions. Results: Analytical non-travelling wave solutions and multi-soliton approximate solutions are derived. The form conditions of soliton molecules are given, and the dynamical characteristics and interactions between special fractional solitons, multi-solitons and soliton molecules are discussed in the periodic inhomogeneous fiber and the exponential dispersion decreasing fiber. Conclusion: Analytical chirp-free and chirped non-traveling wave solutions and multi-soliton approximate solutions including soliton molecules are obtained. Based on these solutions, dynamical characteristics and interactions between special fractional solitons, multi-solitons and soliton molecules are discussed. These theoretical studies are of great help to understand the propagation of optical pulses in fibers.