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Dearomative di- and trifunctionalization of aryl sulfoxides via [5,5]-rearrangement
oleh: Mengjie Hu, Yanping Liu, Yuchen Liang, Taotao Dong, Lichun Kong, Ming Bao, Zhi-Xiang Wang, Bo Peng
Format: | Article |
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Diterbitkan: | Nature Portfolio 2022-08-01 |
Deskripsi
In contrast with well-established dearomatization protocols such as the Birch reduction, sigmatropic rearrangement-based dearomatizations are a less-explored but potentially effective route to saturated compounds. Here, the authors show a [5,5]-rearrangement-enabled dearomatization of aryl sulfoxides.