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This study analyzed the characteristics and distribution of emissions from diesel vehicles that are sold in Korea and satisfy the Euro-6 standards, according to after-treatment systems. To identify the emission distribution of diesel vehicles according to after-treatment systems, results of the certification tests conducted on 266 vehicle models were examined. Results of the certification tests on 86 vehicle models that were manufactured based on the standards for RDE after 2017 were examined according to the engine displacement and power. The emission characteristics of six vehicle models equipped with different types of after-treatment systems were verified through certification tests in the New European Driving Cycle and Worldwide Harmonized Light Vehicle Test Procedure modes and RDE tests, according to the after-treatment systems. Specifically, a chassis dynamometer and an emission analyzer were used in the certification test modes; a portable emissions measurement system was used in the RDE test. The results indicated that the amount of NO_x emissions from diesel vehicles has been constantly decreasing since 2017 due to the implementation of standards for RDE and advancements in after-treatment systems. Furthermore, it was found that selective catalyst reduction systems must be installed in vehicles to satisfy Euro-6 standards for permissible emissions on real-roads.